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Angelina Jolie & Brad Pitt Were Once Caught ‘Making Out’ Reveals Bodyguard (Photo Credit: Instagram/Angelina Jolie)

Brad Pitt met FRIENDS actress Jennifer Aniston in 1998, and the two exchanged vows in a private wedding ceremony on July 29, 2000. But in January 2005, Pitt and Aniston announced they had decided to separate. A while before this, rumours of an affair between Brad Pitt and his Mr and Mrs Smith co-star Angelina Jolie started churning.

Things started heating between Brad Pitt and Angelina Jolie when they starred as assassins/lovers in the 2005 film, Mr and Mrs Smith. When these sparks flew, Brad was still married to Jennifer Aniston and hence both, he and Angelina, denied all rumours related to it.

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The duo insisted things only got physical after Brad left Jen in January 2005. Angelina told Vogue in a 2006 interview, “It took until, really, the end of the shoot for us, I think, to realize that it might mean something more than we’d earlier allowed ourselves to believe.”